Octaarylethylynyl and Octaarylbutadiynyl Phthalocyanines
| dc.contributor.author | Leznoff, Clifford C. | |
| dc.contributor.author | Suchozak, Bohdan | |
| dc.date.accessioned | 2011-01-24T20:31:57Z | |
| dc.date.available | 2011-01-24T20:31:57Z | |
| dc.date.issued | 2001 | |
| dc.description.abstract | 4,5-Diphenylethynylphthalonitrile, 4,5-di(p-tert-butylphenylethynyl)phthalonitrile, 4,5-di(p-neopentoxyphenylethynyl)phthalonitrile, and 4,5-di(p-neopentoxyphenyl-1,3-butadiynyl)phthalonitrile were prepared via 4,5-diiodophthalonitrile and the appropriate alkyne in palladium-catalyzed coupling reactions. Condensation of the above alkynylphthalonitriles with lithium 1-octanolate in 1-octanol afforded the desired polyalkynylphthalocyanines, but only 2,3,9,10,16,17,22,23-octa (p-neopentoxyphenylethynyl)phthalocyanine and 2,3,9,10,16,17, 22,23-octa (p-neopentoxyphenylbutadnyl)phthalocyanine were soluble enough to be suitably characterized. | |
| dc.identifier.citation | C. C. Leznoff and B. Suchozak, “Octaarylethynyl and octaarylbutadiynyl phthalocyanines,” Canadian Journal of Chemistry, vol. 79, no. 5–6, pp. 878–887, May 2001. | en |
| dc.identifier.uri | http://hdl.handle.net/10315/6622 | |
| dc.identifier.uri | https://dx.doi.org/10.1139/v00-186 | |
| dc.language.iso | en | en |
| dc.publisher | Canadian Journal of Chemistry, NRC Research Press | en |
| dc.subject | phthalocyanines | |
| dc.subject | phenylacetylenes | |
| dc.subject | 1-phenyl-1 | |
| dc.subject | 3-butadiynes | |
| dc.title | Octaarylethylynyl and Octaarylbutadiynyl Phthalocyanines | en |
| dc.type | Article | en |