The Use of Isothermal Gas Chromatography for the Determination of Adsorptionenthalpies and entropies of Inorganic Halides at High Temperatures

dc.contributor.authorRudolph, J.
dc.contributor.authorBachmann, K.
dc.date.accessioned2010-02-04T20:04:16Z
dc.date.available2010-02-04T20:04:16Z
dc.date.issued1980
dc.description.abstractGas chromatography was used to determine the adsorption enthalpies and entropies of inorganic chlorides on sslid non-porous adsorhents (silica, alkali metal chlorides, graphite, etc.) at high temperatures (65th1100°K). The results demonstrate that gas chromatography is also a useful method for investigations in the field of inorganic chemistry. The adsorption enthalpies and entropies (or rather, chemisorption enthdpies and entropies) indicate that the adsorption (or chemisorption proCess>i nvolves complex formation between the adsorbed molecules and the adsorbent (coordinative by bonded surface complex).en
dc.identifier.citationJ. Chromatogr., 187, 319-329en
dc.identifier.urihttp://hdl.handle.net/10315/2934
dc.language.isoenen
dc.rights.articlehttp://www.sciencedirect.com/science?_ob=ArticleURL&_udi=B6TG8-453BY0F-8N&_user=866177&_coverDate=01%2F18%2F1980&_rdoc=1&_fmt=high&_orig=search&_sort=d&_docanchor=&view=c&_searchStrId=1193840276&_rerunOrigin=google&_acct=C000045519&_version=1&_urlVersion=0&_userid=866177&md5=dd1832363a52ed809f405b1f6e2a2aefen
dc.rights.journalhttp://www.sciencedirect.com/science/journal/00219673en
dc.titleThe Use of Isothermal Gas Chromatography for the Determination of Adsorptionenthalpies and entropies of Inorganic Halides at High Temperaturesen
dc.typeArticleen

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